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Full Research Article

volume 37 issue 4 (december 2022) : 343-349,   Doi: 10.18805/BKAP505

Dissipation of Lambda-cyhalothrin 5% EC on Brinjal Fruit Grown in Gurugram, Haryana

S
S. Mishra
V
V.K. Pandey
S
S. Bansal
V
Vikash
M
M. Singh
S
S. Alam
L
L.K. Thakur
1Department of Analytical Division, Institute of Pesticide Formulation Technology, Gurugram-122 016, Haryana, India.

  • Submitted04-04-2022|

  • Accepted23-08-2022|

  • First Online 14-09-2022|

  • doi 10.18805/BKAP505

Cite article:- Mishra S., Pandey V.K., Bansal S., Vikash, Singh M., Alam S., Thakur L.K. (2022). Dissipation of Lambda-cyhalothrin 5% EC on Brinjal Fruit Grown in Gurugram, Haryana. Bhartiya Krishi Anusandhan Patrika. 37(4): 343-349. doi: 10.18805/BKAP505.

ABSTRACT

Background: The introduction of synthetic pesticides Lambda-cyhalothrinin for crop protection in general has significantly contributed to increased productivity. Lambda-cyhalothrin have been reported to cause toxic effects on humans, ranging from short-term effects such as headaches and nausea to chronic effects like cancer, reproductive damage and endocrine disruption. Lambda-cyhalothrin is a type-II highly active synthetic pyrethroid insecticide which contains a-cyano group. Lambda-cyhalothrin applied at the rate of 30 g a.i. ha-1 was found to be effective against shoot and fruit borer on brinjal.
Methods: The analytical method for the determination of Lambda-cyhalothrin 5% EC (Test Item) on brinjal was validated as per DG-SANTE 2019 guideline. The field trails including the dissipation study and final residue study were conducted in a randomized block design in open field. As per recommendation, dose of test item (T1= 15 g a.i/ha; T2 = 30 g a.i/ha) were 500 L/hectare for Trial. Lambda-cyhalothrin residues of brinjal samples were determined at 0, 1, 3, 5, 7 and 10 days at both application of recommended and double the recommended dose of test item. 
Result: The analytical method employed for determination of persistence residues of Lambda-cyhalothrin in brinjal was validated and found accurate and precise. The per cent dissipation of Lambda-cyhalothrin for the treatment T1 was 37.22% after 1 day which increased to 96.66% by 10th day, similarly for the double dose (T2) the initial dissipation was 57.14%, which increased to 99.7 % after 10th day. The half-life (T1/2) values of Lambda-cyhalothrin on brinjal were found to be 2.06 and 2.13 days for T1 and T2, respectively. 

REFERENCES


  1. Aydinalp, C., Porca, M.M. (2004). The effects of pesticides in water resources. Journal Central European Agriculture. 5(1): 5-12.

  2. Banerjee, K., Upadhyay, A.K., Adsule, P.G., Patil, S.H., Oulkar, D.P., Jadhav, D.R. (2006). Rate of degradation of lambda- cyhalothrin and methomyl in grapes (Vitis vinifera L.). Food Additives Contaminants. 23(10): 994-999. 

  3. Berrada, H., Fernandez, M., Ruiz, M.J., Molto, J.C., Font, G. (2010). Surveillance of pesticide residues in fruits from Valencia during twenty months (2004/05). Food Control. 21(1): 36-44.

  4. Brady, J.A., Wallender, W.W., Werner, I., Fard, B.M., Zalom, F.G., Oliver, M.N., Wilson B.W., Mata, M.M., Henderson, J.D., Deanovic, L.A., Upadhaya, S. (2006). Pesticide runoff from orchard floors in Davis, California, USA: A comparative analysis of diazinon and esfenvalerate. Agriculture Ecosystems Environment. 115(1-4): 56-68.

  5. Cabras, P., Meloni, M., Cabitza, F., Cubeddu, M. (1989). Pesticide residues in lettuce. 2. Influence of formulation. Journal Agricultural Food Chemistry. 37: 1405-7.

  6. Chen, C., Qian, Y., Chen, Q., Tao, C., Li, C., Li, Y. (2011). Evaluation of pesticide residues in fruits and vegetables from Xiamen, China. Food Control. 22: 1114-20.

  7. Claeys, W.L., Schmit, J.F., Bragard, C., Maghuin-Rogister, G., Pussemier, L., Schiffers, B. (2011). Exposure of several Belgian consumer groups to pesticide residues through fresh fruits and vegetable consumption. Food Control. 22(3-4): 508-16.

  8. DG-SANTE (Directorate-General for Health and Food Safety), (2017). Guidance Document on Analytical Quality Control and Method Validation Procedures for Pesticide Residues and Analysis in Food and Feed. Document No. SANTE/11813/ 2017 European Commission 21-22. November 2017, rev. 0. (Accessed on June, 2019).

  9. Document SANCO/12571/2013. Guidance Document on Analytical Quality Control and Validation Procedures for Pesticide Residue Analysis in Food and Feed.

  10. Food Safety and Standards Authority of India (FSSAI), (2019). Gazette notification on food safety and standards (contaminants, toxins and residues) amendment regulation related to MRL of pesticide. The Gazette of India: Extraordinary [Part III-Section 4], 24: 1-51. 

  11. Hanafi, A., Garau, V.L., Caboni, P., Sarais, G., Cabras, P. (2010). Minor crops for export: a case study of boscalid, pyraclostrobin, lufenuron and lambda-cyhalothrin residue levels on green beans and spring onions in Egypt. Journal Environment Science Health B. 45(6): 493-500. 

  12. Isenring, R., Madeley, J. (2006). Paraquat: Unacceptable Health Risks for Users. 3rd ed. London, UK: Pesticide Action Network UK.

  13. Jayakrishnan, S., Dikshit, A.K., Singh, J.P., Pachauri, D.C., (2005). Dissipation of lambda-cyhalothrin on tomato (Lycopersicon esculentum Mill.) and removal of its residues by different washing processes and steaming. Bulletin Environment Contamination Toxicology. 75(2): 324-328. 

  14. Joint FAO/WHO Codex Alimentarius Commission Programme. (2003). Codex Alimentarius: Food Hygiene, Basic Texts; Food and Agriculture Organization: Rome, Italy.

  15. Lu, M-X., Jiang, W.W., Wang, J.L., Jian, Q., Shen, Y., et al. (2014). Persistence and Dissipation of Chlorpyrifos in Brassica Chinensis, Lettuce, Celery, Asparagus Lettuce, Eggplant and Pepper in a Greenhouse. 9(6): e100556. 

  16. Malhat, F., El Sharkawi, H., Loutfy, N. and Ahmed, M. (2014-a). Field dissipation and health hazard assessment of fenhexamid on egyptian grapes. Toxicological and Environmental Chemistry. 96(5): 722-729.

  17. Malhat, F., Hassan, A. (2011). Level and fate of etoxazole in green bean (Phaseolus vulgaris). Bulletin Environment Contamination  Toxicology. 87(2): 190-3. 

  18. Pretty, J., Bharucha, Z.P. (2015). Integrated pest management for sustainable intensification of agriculture in Asia and Africa. Insects. 6: 152-182. 

  19. Voutsas, E., Vavva, C., Magoulas, K., Tassios, D. (2005). Estimation of the volatilization of organic compounds from soil surfaces. Chemosphere. 58(6): 751-8.
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    Full Research Article

    volume 37 issue 4 (december 2022) : 343-349,   Doi: 10.18805/BKAP505

    Dissipation of Lambda-cyhalothrin 5% EC on Brinjal Fruit Grown in Gurugram, Haryana

    S
    S. Mishra
    V
    V.K. Pandey
    S
    S. Bansal
    V
    Vikash
    M
    M. Singh
    S
    S. Alam
    L
    L.K. Thakur
    1Department of Analytical Division, Institute of Pesticide Formulation Technology, Gurugram-122 016, Haryana, India.

    • Submitted04-04-2022|

    • Accepted23-08-2022|

    • First Online 14-09-2022|

    • doi 10.18805/BKAP505

    Cite article:- Mishra S., Pandey V.K., Bansal S., Vikash, Singh M., Alam S., Thakur L.K. (2022). Dissipation of Lambda-cyhalothrin 5% EC on Brinjal Fruit Grown in Gurugram, Haryana. Bhartiya Krishi Anusandhan Patrika. 37(4): 343-349. doi: 10.18805/BKAP505.

    ABSTRACT

    Background: The introduction of synthetic pesticides Lambda-cyhalothrinin for crop protection in general has significantly contributed to increased productivity. Lambda-cyhalothrin have been reported to cause toxic effects on humans, ranging from short-term effects such as headaches and nausea to chronic effects like cancer, reproductive damage and endocrine disruption. Lambda-cyhalothrin is a type-II highly active synthetic pyrethroid insecticide which contains a-cyano group. Lambda-cyhalothrin applied at the rate of 30 g a.i. ha-1 was found to be effective against shoot and fruit borer on brinjal.
    Methods: The analytical method for the determination of Lambda-cyhalothrin 5% EC (Test Item) on brinjal was validated as per DG-SANTE 2019 guideline. The field trails including the dissipation study and final residue study were conducted in a randomized block design in open field. As per recommendation, dose of test item (T1= 15 g a.i/ha; T2 = 30 g a.i/ha) were 500 L/hectare for Trial. Lambda-cyhalothrin residues of brinjal samples were determined at 0, 1, 3, 5, 7 and 10 days at both application of recommended and double the recommended dose of test item. 
    Result: The analytical method employed for determination of persistence residues of Lambda-cyhalothrin in brinjal was validated and found accurate and precise. The per cent dissipation of Lambda-cyhalothrin for the treatment T1 was 37.22% after 1 day which increased to 96.66% by 10th day, similarly for the double dose (T2) the initial dissipation was 57.14%, which increased to 99.7 % after 10th day. The half-life (T1/2) values of Lambda-cyhalothrin on brinjal were found to be 2.06 and 2.13 days for T1 and T2, respectively. 

    REFERENCES


    1. Aydinalp, C., Porca, M.M. (2004). The effects of pesticides in water resources. Journal Central European Agriculture. 5(1): 5-12.

    2. Banerjee, K., Upadhyay, A.K., Adsule, P.G., Patil, S.H., Oulkar, D.P., Jadhav, D.R. (2006). Rate of degradation of lambda- cyhalothrin and methomyl in grapes (Vitis vinifera L.). Food Additives Contaminants. 23(10): 994-999. 

    3. Berrada, H., Fernandez, M., Ruiz, M.J., Molto, J.C., Font, G. (2010). Surveillance of pesticide residues in fruits from Valencia during twenty months (2004/05). Food Control. 21(1): 36-44.

    4. Brady, J.A., Wallender, W.W., Werner, I., Fard, B.M., Zalom, F.G., Oliver, M.N., Wilson B.W., Mata, M.M., Henderson, J.D., Deanovic, L.A., Upadhaya, S. (2006). Pesticide runoff from orchard floors in Davis, California, USA: A comparative analysis of diazinon and esfenvalerate. Agriculture Ecosystems Environment. 115(1-4): 56-68.

    5. Cabras, P., Meloni, M., Cabitza, F., Cubeddu, M. (1989). Pesticide residues in lettuce. 2. Influence of formulation. Journal Agricultural Food Chemistry. 37: 1405-7.

    6. Chen, C., Qian, Y., Chen, Q., Tao, C., Li, C., Li, Y. (2011). Evaluation of pesticide residues in fruits and vegetables from Xiamen, China. Food Control. 22: 1114-20.

    7. Claeys, W.L., Schmit, J.F., Bragard, C., Maghuin-Rogister, G., Pussemier, L., Schiffers, B. (2011). Exposure of several Belgian consumer groups to pesticide residues through fresh fruits and vegetable consumption. Food Control. 22(3-4): 508-16.

    8. DG-SANTE (Directorate-General for Health and Food Safety), (2017). Guidance Document on Analytical Quality Control and Method Validation Procedures for Pesticide Residues and Analysis in Food and Feed. Document No. SANTE/11813/ 2017 European Commission 21-22. November 2017, rev. 0. (Accessed on June, 2019).

    9. Document SANCO/12571/2013. Guidance Document on Analytical Quality Control and Validation Procedures for Pesticide Residue Analysis in Food and Feed.

    10. Food Safety and Standards Authority of India (FSSAI), (2019). Gazette notification on food safety and standards (contaminants, toxins and residues) amendment regulation related to MRL of pesticide. The Gazette of India: Extraordinary [Part III-Section 4], 24: 1-51. 

    11. Hanafi, A., Garau, V.L., Caboni, P., Sarais, G., Cabras, P. (2010). Minor crops for export: a case study of boscalid, pyraclostrobin, lufenuron and lambda-cyhalothrin residue levels on green beans and spring onions in Egypt. Journal Environment Science Health B. 45(6): 493-500. 

    12. Isenring, R., Madeley, J. (2006). Paraquat: Unacceptable Health Risks for Users. 3rd ed. London, UK: Pesticide Action Network UK.

    13. Jayakrishnan, S., Dikshit, A.K., Singh, J.P., Pachauri, D.C., (2005). Dissipation of lambda-cyhalothrin on tomato (Lycopersicon esculentum Mill.) and removal of its residues by different washing processes and steaming. Bulletin Environment Contamination Toxicology. 75(2): 324-328. 

    14. Joint FAO/WHO Codex Alimentarius Commission Programme. (2003). Codex Alimentarius: Food Hygiene, Basic Texts; Food and Agriculture Organization: Rome, Italy.

    15. Lu, M-X., Jiang, W.W., Wang, J.L., Jian, Q., Shen, Y., et al. (2014). Persistence and Dissipation of Chlorpyrifos in Brassica Chinensis, Lettuce, Celery, Asparagus Lettuce, Eggplant and Pepper in a Greenhouse. 9(6): e100556. 

    16. Malhat, F., El Sharkawi, H., Loutfy, N. and Ahmed, M. (2014-a). Field dissipation and health hazard assessment of fenhexamid on egyptian grapes. Toxicological and Environmental Chemistry. 96(5): 722-729.

    17. Malhat, F., Hassan, A. (2011). Level and fate of etoxazole in green bean (Phaseolus vulgaris). Bulletin Environment Contamination  Toxicology. 87(2): 190-3. 

    18. Pretty, J., Bharucha, Z.P. (2015). Integrated pest management for sustainable intensification of agriculture in Asia and Africa. Insects. 6: 152-182. 

    19. Voutsas, E., Vavva, C., Magoulas, K., Tassios, D. (2005). Estimation of the volatilization of organic compounds from soil surfaces. Chemosphere. 58(6): 751-8.
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